Corey-Kim Oxidation

Corey-Kim Oxidation

The Corey-Kim Oxidation Allows The Synthesis Of Aldehydes And Ketones From Primary Alcohols And Secondary Alcohols, Respectively.


Mechanism Of The Corey-Kim Oxidation

Dimethylchlorosulphonium Ion Is Generated in Situ from NCS And DMS:

The Following Steps Are Comparable To The Swern Oxidation:

ecent Literature


New Odorless Method For The Corey–Kim And Swern Oxidations Utilizing Dodecyl Methyl Sulfide (Dod-S-Me)
S.-I. Ohsugia, K. Nishidea, K. Oonob, K. Okuyamab, M. Fudesakaa, S. Kodamaa, M. Node, Tetrahedron200359, 8393-8398.


The Fluorous Swern And Corey-Kim Reaction: Scope And Mechanism
D. Crich, S. Neelamkavil, Tetrahedron2002, 58, 3865-3870.